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Выставка к Международной ежегодной конференции "81st Annual Meeeting of The Meteoritical Society"

Журнальные статьи

1. S04675
Brownlee D., Joswiak D., Matrajt G. Overview of the rocky component of Wild 2 comet samples: Insight into the early solar system, relationship with meteoritic materials and the differences between comets and asteroids // Meteorit. Planet. Sci. 2012. Vol. 47, № 4. P. 453–470.

The solid 210 mu m samples of comet Wild 2 provide a limited but direct view of the solar nebula solids that accreted to form Jupiter family comets. The samples collected by the Stardust mission are dominated by high-temperature materials that are closely analogous to meteoritic components. These materials include chondrule and CAI-like fragments. Five presolar grains have been discovered, but it is clear that isotopically anomalous presolar grains are only a minor fraction of the comet. Although uncertain, the presolar grain content is perhaps higher than found in chondrites and most interplanetary dust particles. It appears that the majority of the analyzed Wild 2 solids were produced in high-temperature rock forming environments, and they were then transported past the orbit of Neptune, where they accreted along with ice and organic components to form comet Wild 2. We hypothesize that Wild 2 rocky components are a sample of a ubiquitously distributed flow of nebular solids that was accreted by all bodies including planets and meteorite parent bodies. A primary difference between asteroids and the rocky content of comets is that comets are dominated by this widely distributed component. Asteroids contain this component, but are dominated by locally made materials that give chondrite groups their distinctive properties. Because of the large radial mixing in this scenario, it seems likely that most comets contain a similar mix of rocky materials. If this hypothesis is correct, then properties such as oxygen isotopes and minor element abundances in olivine, should have a wider dispersion than in any chondrite group, and this may be a characteristic property of primitive outer solar system bodies made from widely transported components.

http://dx.doi.org/10.1111%2Fj.1945-5100.2012.01339.x

2. U12332
Goldmann A. et al. The uranium isotopic composition of the Earth and the Solar System // Geochim. Cosmochim. Acta. 2015. Vol. 148. P. 145–158.

Recent high-precision mass spectrometric studies of the uranium isotopic composition of terrestrial and meteoritic materials have shown significant variation in the U-238/U-235 ratio, which was previously assumed to be invariant (=137.88). In this study, we have investigated 27 bulk meteorite samples from different meteorite groups and types, including carbonaceous (CM1 and CV3), enstatite (EH4) and ordinary (H-, L-, and LL-) chondrites, as well as a variety of achondrites (angrites, eucrites, and ungrouped) to constrain the distribution of U isotopic heterogeneities and to determine the average U-238/U-235 for the Solar System. The investigated bulk meteorites show a range in U-238/U-235 between 137.711 and 137.891 (1.3 parts per thousand) with the largest variations among ordinary chondrites (OCs). However, the U isotope compositions of 20 of the 27 meteorites analyzed here overlap within analytical uncertainties with the narrow range defined by terrestrial basalts (137.778-137.803), which are likely the best representatives for the U isotope composition of the bulk silicate Earth. Furthermore, the average U-238/U-235 of all investigated meteorite groups overlaps with that of terrestrial basalts (137.795 +/- 0.013). The bulk meteorite samples studied here do not show a negative correlation of U-238/U-235 with Nd/U or Th/U (used as proxies for the Cm/U ratio), as would be expected if radiogenic U-235 was generated by the decay of extant Cm-247 in the early Solar System. Rather, ordinary chondrites show a positive correlation of U-238/U-235 with Nd/U and with 1/U. The following conclusions can be drawn from this study: (1) The Solar System has a broadly homogeneous U isotope composition, and bulk samples of only a limited number of meteorites display detectable U isotope variations; (2) Bulk planetary differentiation has no significant effect on the U-238/U-235 ratio since the Earth, achondrites, and chondrites have indistinguishable U isotope compositions in average. (3) The cause of U isotopic variation in Solar System materials remains enigmatic; however, both the decay of Cm-247 and isotope fractionation are likely responsible for the U isotopic variations observed in CAIs and ordinary chondrites, respectively. The average U-238/U-235 of the investigated meteorite groups (including data compiled from the literature) and terrestrial basalts is 137.794 +/- 0.027 (at a 95% student's t confidence level, including all propagated uncertainties) and represents the best estimate for the Uisotope composition of the Earth and the Solar System. This value may be used for U-Pb and Pb-Pb dating of Solar System materials, provided the precise U isotope composition of the sample is unknown. Compared to Pb-Pb ages that were determined with the previously assumed value for U-238/U-235 (137.88), this new value results in an age adjustment of -0.9 Ma.

http://dx.doi.org/10.1016%2Fj.gca.2014.09.008

3. U01624
Jones R.H., McCubbin F.M., Guan Y. Phosphate minerals in the H group of ordinary chondrites, and fluid activity recorded by apatite heterogeneity in the Zag H3-6 regolith breccia // Am. Miner. 2016. Vol. 101, № 11. P. 2452–2467.

Phosphate minerals in ordinary chondrites provide a record of fluids that were present during metamorphic heating of the chondrite parent asteroids. We have carried out a petrographic study of the phosphate minerals, merrillite and apatite, in metamorphosed H group ordinary chondrites of petrologic type 4-6, to understand development of phosphate minerals and associated fluid evolution during metamorphism. In unbrecciated chondrites, apatite is Cl rich and shows textural evolution from fine-grained apatite-merrillite assemblages in type 4 toward larger, uniform grains in type 6. The Cl/F ratio in apatite shows a similar degree of heterogeneity in all petrologic types, and no systematic change in compositions with metamorphic grade, which suggests that compositions in each meteorite are dictated by localized conditions, possibly because of a limited fluid/rock ratio. The development of phosphate minerals in H chondrites is similar to that of L and LL chondrites, despite the fact that feldspar equilibration resulting from albitization is complete in H4 chondrites but not in L4 or LL4 chondrites. This suggests that albitization took place during an earlier period of the metamorphic history than that recorded by preserved apatite compositions, and chemical equilibrium was not achieved throughout the H chondrite parent body or bodies during the late stages of metamorphism. A relict igneous clast in the H5 chondrite, Oro Grande has apatite rims on relict phenocrysts of (possibly) diopside that have equilibrated with the host chondrite. Apatite in the Zag H3-6 regolith breccia records a complex fluid history, which is likely related to the presence of halite in this meteorite. The porous dark H4 matrix of Zag, where halite is observed, has a high apatite/merrillite ratio, and apatite is extremely Cl rich. One light H6 clast contains similarly Cl-rich apatite. In a second light H6 clast, apatite compositions are very heterogeneous and more F-rich. Apatites in both H4 matrix and H6 clasts have very low H2O contents. Heterogeneous apatite compositions in Zag record multiple stages of regolith processing and shock at the surface of the H chondrite parent body, and apatite records either the passage of fluids of variable compositions resulting from different impact-related processes, or the passage of a single fluid whose composition evolved as it interacted with the chondrite regolith. Unraveling the history of apatite can potentially help to interpret the internal structure of chondrite parent bodies, with implications for physical and mechanical properties of chondritic asteroids. The behavior of halogens recorded by apatite is important for understanding the behavior of volatile elements in general: if impact-melt materials close to the surface of a chondritic asteroid are readily degassed, the volatile inventories of terrestrial planets could be considerably more depleted than the CI carbonaceous chondrite abundances that are commonly assumed.

http://dx.doi.org/10.2138%2Fam-2016-5728

4. U01624
Ma C., Krot A.N. Hutcheonite, Ca3Ti2(SiAl2)O-12, a new garnet mineral from the Allende meteorite: An alteration phase in a Ca-Al-rich inclusion // Am. Miner. 2014. Vol. 99, № 4. P. 667–670.

Hutcheonite (IMA 2013-029), Ca3Ti2(SiAl2)O-12, is a new garnet mineral that occurs with monticellite, grossular, and wadalite in secondary alteration areas along sonic cracks between primary melilite, spinet, and Ti.Al-diopside in a Type B I Fractionation and Unidentified Nuclear effects (FUN) Ca-Al-rich inclusion (CAI) Egg-3 from the Allende CV (Vigarano type) carbonaceous chondrite. The mean chemical composition of type hutcheonite by electron probe microanalysis is (wt%) CaO 34.6, TiO2 25.3, SiO2 20.9, Al2O3 15.7. MgO 2.1, FeO 0.7, V2O3 0.5, total 99.8, giving rise to an empirical formula of Ca-2.99(Ti1.534+Mg0.25Al0.17F0.052+V0.033+)(Si1.68Al1.32)O-12. The end-member formula is Ca3Ti2(SiAl2)O-12. g/cm(3). Hutcheonite has the la (3) over bard garnet structure with a = 11.843 angstrom. V = 1661.06 angstrom(3), and Z = 8, as revealed by electron backscatter diffraction. The calculated density using the measured composition is 3.86 Hutcheonite is a new secondary phase in Allende, apparently formed by iron-alkali-halogen metasomatic alteration of the primary CAI phases like melilite, perovskite, and Ti,Al-diopside on the CV chondrite parent asteroid. Formation of the secondary Ti-rich minerals like hutcheonite during the metasomatic alteration of the Allende CAIs suggests some mobility of Ti during the alteration. The mineral name is in honor of Ian D. Hutcheon, a cosmochemist at Lawrence Livermore National Laboratory, California. U.S.A.

http://dx.doi.org/10.2138%2Fam.2014.4761

5. U01624
Ma C., Krot A.N., Nagashima K. Addibischoffite, Ca2Al6Al6O20, a new calcium aluminate mineral from the Acfer 214 CH carbonaceous chondrite: A new refractory phase from the solar nebula // Am. Miner. 2017. Vol. 102, № 7. P. 1556–1560.

Addibischoffite (IMA 2015-006), Ca2Al6Al6O20, is a new calcium aluminate mineral that occurs with hibonite, perovskite, kushiroite, Ti-kushiroite, spinel, melilite, anorthite, and FeNi-metal in the core of a Ca-Al-rich inclusion (CAI) in the Acfer 214 CH3 carbonaceous chondrite. The mean chemical composition of type addibischoffite measured by electron probe microanalysis is (wt%) Al2O3 44.63, CaO 15.36, SiO2 14.62, V2O3 10.64, MgO 9.13, Ti2O3 4.70, FeO 0.46, total 99.55, giving rise to an empirical formula of (Ca-2.00)(Al2.55Mg1.73V1.083+Ti0.503+Ca0.09Fe0.052+)(Sigma 6.01)(Al4.14Si1.86)O-20. The general formula is Ca-2(Al, Mg,V,Ti)(6)(Al, Si)(6)O-20. The end-member formula is Ca2Al6Al6O20. Addibischoffite has the P (1) over bar aenigmatite structure with a = 10.367 angstrom, b = 10.756 angstrom, c = 8.895 angstrom, alpha = 106.0 degrees, beta = 96.0 degrees, gamma = 124.7 degrees, V = 739.7 angstrom(3), and Z = 2, as revealed by electron backscatter diffraction. The calculated density using the measured composition is 3.41 g/cm(3). Addibischoffite is a new member of the warkite (Ca2Sc6Al6O20) group and a new refractory phase formed in the solar nebula, most likely as a result of crystallization from an O-16-rich Ca, Al-rich melt under high-temperature (similar to 1575 degrees C) and low-pressure (similar to 10(-4) to 10(-5) bar) conditions in the CAI-forming region near the protosun, providing a new puzzle piece toward understanding the details of nebular processes. The name is in honor of Addi Bischoff, cosmochemist at University of Munster, Germany, for his many contributions to research on mineralogy of carbonaceous chondrites, including CAIs in CH chondrites.

http://dx.doi.org/10.2138%2Fam-2017-6032

6. S04675
Munoz Caro G.M. et al. A potentially new type of nonchondritic interplanetary dust particle with hematite, organic carbon, amorphous Na,Ca-aluminosilicate, and FeO-spheres // Meteorit. Planet. Sci. 2012. Vol. 47, № 2. P. 248–261.

We used a combination of different analytical techniques to study particle W7190-D12 using microinfrared spectroscopy, micro-Raman spectroscopy, and field emission scanning electron microscopy (FESEM) energy dispersive X-ray spectroscopy (EDS). The particle consists mainly of hematite (a-Fe2O3) with considerable variations in structural disorder. It further contains amorphous (Na,K)-bearing Ca,Al-silicate and organic carbon. Iron-bearing spherules (<150 nm in diameter) cover the surface of this particle. At local sites of structural disorder at the hematite surface, the hematite spheres were reduced to FeO in the presence of organic carbons forming FeO-spheres. However, metallic Fe spheres cannot be excluded based on the available data. To the best of our knowledge, this particle is the first detection of such spherules at the surface of a stratospheric dust particle. Although there is no definitive evidence for an extraterrestrial origin of particle W7190-D12, we suggest that it could be an IDP that had moved away from the asteroid-forming region of the early solar system into the outer solar system of the accreting Kuiper Belt objects. After it was released from a Jupiter family comet, this particle became part of the zodiacal cloud. Atmospheric entry flash-heating caused (1) the formation of microenvironments of reduced iron oxide when indigenous carbon materials reacted with hematite covering its surface resulting in the formation of FeO-spheres and (2) Na-loss from Na,Al-plagioclase. The particle of this study, and other similar particles on this collector, may represent a potentially new type of nonchondritic IDPs associated with Jupiter family comets, although an origin in the asteroid belt cannot be ignored.

http://dx.doi.org/10.1111%2Fj.1945-5100.2011.01323.x

7. S04675
Plado J. Meteorite impact craters and possibly impact-related structures in Estonia // Meteorit. Planet. Sci. 2012. Vol. 47, № 10. P. 1590–1605.

Three structures (Neugrund, Kardla, and Kaali) of proven impact origin make Estonia the most cratered country in the world by area. In addition, several candidate impact structures exist, waiting for future studies to determine their origin. This article is an overview of these proven and possible impact structures, including some breccia layers. It summarizes the information and descriptions of the morphology; geological characteristics; and mineralogical, chemical, and geophysical data available in the literature. The overview was prepared to make information in many earlier publications in local journals (many of which had been published in Estonian or Russian) accessible to the international community. This review summarizes the facts and observations in a historical fashion, summarizing the current state of knowledge with some additional comments, and providing the references.

http://dx.doi.org/10.1111%2Fj.1945-5100.2012.01422.x

8. U08341
Ruzicka A. Silicate-bearing iron meteorites and their implications for the evolution of asteroidal parent bodies // Chem Erde-Geochem. 2014. Vol. 74, № 1. P. 3–48.

Silicate-bearing iron meteorites differ from other iron meteorites in containing variable amounts of silicates, ranging from minor to stony-iron proportions (similar to 50%). These irons provide important constraints on the evolution of planetesimals and asteroids, especially with regard to the nature of metal-silicate separation and mixing. I present a review and synthesis of available data, including a compilation and interpretation of host metal trace-element compositions, oxygen-isotope compositions, textures, mineralogy, phase chemistries, and bulk compositions of silicate portions, ages of silicate and metal portions, and thermal histories. Case studies for the petrogeneses of igneous silicate lithologies from different groups are provided. Silicate-bearing irons were formed on multiple parent bodies under different conditions. The IAB/IIICD irons have silicates that are mainly chondritic in composition, but include some igneous lithologies, and were derived from a volatile-rich asteroid that underwent small amounts of silicate partial melting but larger amounts of metallic melting. A large proportion of IIE irons contain fractionated alkali-silica-rich inclusions formed as partial melts of chondrite, although other IIE irons have silicates of chondritic composition. The IIEs were derived from an H-chondrite-like asteroid that experienced more significant melting than the IAB asteroid. The two stony-iron IVAs were derived from an extensively melted and apparently chemically processed L or LL-like asteroid that also produced a metallic core. Ungrouped silicate-bearing irons were derived from seven additional asteroids. Hf-W age data imply that metal-silicate separation occurred within 0-10 Ma of CAI formation for these irons, suggesting internal heating by Al-26. Chronometers were partly re-set at later times, mainly earlier for the IABs and later for the IIEs, including one late (3.60 +/- 0.15 Ga) strong impact that affected the "young silicate" IIEs Watson (unfractionated silicate, and probable impact melt), Netschaevo (unfractionated, and metamorphosed), and Kodaikanal (fractionated). Kodaikanal probably did not undergo differentiation in this late impact, but the similar ages of the "young silicate" IIEs imply that relatively undifferentiated and differentiated materials co-existed on the same asteroid. The thermal histories and petrogeneses of fractionated IIE irons and IVA stony irons are best accommodated by a model of disruption and reassembly of partly molten asteroids.

http://dx.doi.org/10.1016%2Fj.chemer.2013.10.001

9. S04675
Sanders I.S., Scott E.R.D. The origin of chondrules and chondrites: Debris from low-velocity impacts between molten planetesimals? // Meteorit. Planet. Sci. 2012. Vol. 47, № 12. P. 2170–2192.

We investigate the hypothesis that many chondrules are frozen droplets of spray from impact plumes launched when thin-shelled, largely molten planetesimals collided at low speed during accretion. This scenario, here dubbed splashing, stems from evidence that such planetesimals, intensely heated by 26Al, were abundant in the protoplanetary disk when chondrules were being formed approximately 2 Myr after calcium-aluminum-rich inclusions (CAIs), and that chondrites, far from sampling the earliest planetesimals, are made from material that accreted later, when 26Al could no longer induce melting. We show how splashing is reconcilable with many features of chondrules, including their ages, chemistry, peak temperatures, abundances, sizes, cooling rates, indented shapes, relict grains, igneous rims, and metal blebs, and is also reconcilable with features that challenge the conventional view that chondrules are flash-melted dust-clumps, particularly the high concentrations of Na and FeO in chondrules, but also including chondrule diversity, large phenocrysts, macrochondrules, scarcity of dust-clumps, and heating. We speculate that type I (FeO-poor) chondrules come from planetesimals that accreted early in the reduced, partially condensed, hot inner nebula, and that type II (FeO-rich) chondrules come from planetesimals that accreted in a later, or more distal, cool nebular setting where incorporation of water-ice with high ?17O aided oxidation during heating. We propose that multiple collisions and repeated re-accretion of chondrules and other debris within restricted annular zones gave each chondrite group its distinctive properties, and led to so-called complementarity and metal depletion in chondrites. We suggest that differentiated meteorites are numerically rare compared with chondrites because their initially plentiful molten parent bodies were mostly destroyed during chondrule formation.

http://dx.doi.org/10.1111%2Fmaps.12002

10. U12332
Shahar A. et al. Sulfur-controlled iron isotope fractionation experiments of core formation in planetary bodies // Geochim. Cosmochim. Acta. 2015. Vol. 150. P. 253–264.

A series of high pressure and temperature experiments were conducted to better constrain the Fe isotope fractionation during core-mantle differentiation in planetesimal and planetary bodies. Synthetic mixtures of oxides and metal having varying amounts of sulfur, approximating terrestrial and Martian compositions, were melted at 1-2 GPa and 1650 degrees C. Iron isotopic equilibrium between the resulting metal and glass run products was verified for all experiments using the three-isotope technique. Purified Fe from metal and glass was analyzed by multiple-collector ICP-MS in high resolution mode. Iron alloy and silicate glass show a well-resolved Delta Fe-57(metal-silicate) of +0.12 +/- 0.04 parts per thousand in a sulfur-free system. Isotope fractionation increases with sulfur content to +0.43 +/- 0.03 parts per thousand at 18 wt.% sulfur in the metal. These results cannot be easily interpreted within the context of known Fe isotope ratios in most natural samples of planetary and asteroidal mantles and therefore suggest more complex processes affected the Fe isotope fractionation therein. However, to reconcile Martian meteorite iron isotopic signatures with geophysical models using this new experimental data requires a smaller amount of sulfur in the Martian core than previous estimates, with an upper limit of similar to 8 wt.%.

http://dx.doi.org/10.1016%2Fj.gca.2014.08.011

11. U27732
Tempesta G. et al. New insights on the Dronino iron meteorite by double-pulse micro-Laser-Induced Breakdown Spectroscopy // Spectrochimica Acta Part B: Atomic Spectroscopy. 2018. Vol. 144. P. 75–81.

Two fragments of an iron meteorite shower named Dronino were characterized by a novel technique, i.e. Double-Pulse micro-Laser Induced Breakdown Spectroscopy (DP-?LIBS) combined with optical microscope. This technique allowed to perform a fast and detailed analysis of the chemical composition of the fragments and permitted to determine their composition, the alteration state differences and the cooling rate of the meteorite. Qualitative analysis indicated the presence of Fe, Ni and Co in both fragments, whereas the elements Al, Ca, Mg, Si and, for the first time Li, were detected only in one fragment and were related to its post-falling alteration and contamination by weathering processes. Quantitative analysis data obtained using the calibration-free (CF) - LIBS method showed a good agreement with those obtained by traditional methods generally applied to meteorite analysis, i.e. Electron Dispersion Spectroscopy - Scanning Electron Microscopy (EDS-SEM), also performed in this study, and Electron Probe Microanalysis (EMPA) (literature data). The local and coupled variability of Ni and Co (increase of Ni and decrease of Co) determined for the unaltered portions exhibiting plessite texture, suggested the occurrence of solid state diffusion processes under a slow cooling rate for the Dronino meteorite.

http://dx.doi.org/10.1016%2Fj.sab.2018.03.014

12. S04675
Urbini S. et al. Geological and geophysical investigation of Kamil crater, Egypt // Meteorit. Planet. Sci. 2012. Vol. 47, № 11. P. 1842–1868.

We detail the Kamil crater (Egypt) structure and refine the impact scenario, based on the geological and geophysical data collected during our first expedition in February 2010. Kamil Crater is a model for terrestrial small-scale hypervelocity impact craters. It is an exceptionally well-preserved, simple crater with a diameter of 45 m, depth of 10 m, and rayed pattern of bright ejecta. It occurs in a simple geological context: flat, rocky desert surface, and target rocks comprising subhorizontally layered sandstones. The high depth-to-diameter ratio of the transient crater, its concave, yet asymmetric, bottom, and the fact that Kamil Crater is not part of a crater field confirm that it formed by the impact of a single iron mass (or a tight cluster of fragments) that fragmented upon hypervelocity impact with the ground. The circular crater shape and asymmetries in ejecta and shrapnel distributions coherently indicate a direction of incidence from the NW and an impact angle of approximately 30 to 45 degrees. Newly identified asymmetries, including the off-center bottom of the transient crater floor downrange, maximum overturning of target rocks along the impact direction, and lower crater rim elevation downrange, may be diagnostic of oblique impacts in well-preserved craters. Geomagnetic data reveal no buried individual impactor masses > 100 kg and suggest that the total mass of the buried shrapnel > 100 g is approximately 1050-1700 kg. Based on this mass value plus that of shrapnel > 10 g identified earlier on the surface during systematic search, the new estimate of the minimum projectile mass is approximately 5 t.

http://dx.doi.org/10.1111%2Fmaps.12023

13. U01624
Ward D. et al. Trace element inventory of meteoritic Ca-phosphates // Am. Miner. 2017. Vol. 102, № 9. P. 1856–1880.

Most extraterrestrial samples feature the two accessory Ca-phosphates (apatite-group minerals and merrillite), which are important carrier phases of the rare earth elements (REE). The trace-element concentrations (REE, Sc, Ti, V, Cr, Mn, Co, As, Rb, Sr, Y, Zr, Nb, Ba, Hf, Ta, Pb, Th, and U) of selected grains were analyzed by LA-ICP-MS and/or SIMS (REE only). This systematic investigation includes 99 apatite and 149 merrillite analyses from meteorites deriving from various asteroidal bodies including 1 carbonaceous chondrite, 8 ordinary chondrites, 3 acapulcoites, 1 winonaite, 2 eucrites, 5 shergottites, 1 ureilitic trachyandesite, 2 mesosiderites, and 1 silicate-bearing IAB iron meteorite. Although Ca-phosphates predominantly form in metamorphic and/or metasomatic reactions, some are of igneous origin. As late-stage phases that often incorporate the vast majority of their host's bulk REE budget, the investigated Ca-phosphates have REE enrichments of up to two orders of magnitude compared to the host rock's bulk concentrations. Within a single sample, each phosphate species displays a uniform REE-pattern, and variations are mainly restricted to their enrichment, therefore indicating similar formation conditions. Exceptions are brecciated samples, i.e., the Adzhi-Bogdo (LL3-6) ordinary chondrite. Despite this uniformity within single samples, distinct meteorite groups do not necessarily have unique REE-patterns. Four basic shapes dominate the REE patterns of meteoritic Ca-phosphates: (1) flat patterns, smoothly decreasing from La-Lu with prominent negative Eu anomalies (acapulcoites, eucrites, apatite from the winonaite and the ureilitic trachyandesite, merrillite from ordinary chondrites); (2) unfractionated patterns, with only minor or no anomalies (mesosiderites, enriched shergottites, IAB-iron meteorite); (3) LREE-enriched patterns, with either positive or slightly negative Eu anomalies (chondritic apatite); and (4) strongly LREE-depleted patterns, with negative Eu anomalies (depleted shergottites). The patterns do not correlate with the grade of metamorphism (petrologic type), specific adjacent mineral assemblages or with Ca-phosphate grain size. Neither the proportions of different REE, nor particular REE patterns themselves are universally correlated to a specific formation mechanism yet Eu (i.e., magnitude of the Eu anomaly) is a sensitive indicator to evaluate the timing of plagioclase and phosphate crystallization. Based on our data, U and Th abundances in apatite increase (almost linearly) with the grade of metamorphism, as well as with the differentiation of their host rock.

http://dx.doi.org/10.2138%2Fam-2017-6056

14. U12332
Yang J. et al. Thermal and collisional history of Tishomingo iron meteorite: More evidence for early disruption of differentiated planetesimals // Geochim. Cosmochim. Acta. 2014. Vol. 124. P. 34–53.

Tishomingo is a chemically and structurally unique iron with 32.5 wt.% Ni that contains 20% residual taenite and 80% martensite plates, which formed on cooling to between -75 and -200 degrees C, probably the lowest temperature recorded by any meteorite. Our studies using transmission (TEM) and scanning electron microscopy (SEM), X-ray microanalysis (AEM) and electron backscatter diffraction (EBSD) show that martensite plates in Tishomingo formed in a single crystal of taenite and decomposed during reheating forming 10-100 nm taenite particles with similar to 50 wt.% Ni, kamacite with similar to 4 wt.%Ni, along with martensite or taenite with 32 wt.% Ni. EBSD data and experimental constraints show that Tishomingo was reheated to 320-400 degrees C for about a year transforming some martensite to kamacite and to taenite particles and some martensite directly to taenite without composition change. Fizzy-textured intergrowths of troilite, kamacite with 2.7 wt.% Ni and 2.6 wt.% Co, and taenite with 56 wt.% Ni and 0.15 wt.% Co formed by localized shock melting. A single impact probably melted the sub-mm sulfides, formed stishovite, and reheated and decomposed the martensite plates. Tishomingo and its near-twin Willow Grove, which has 28 wt.% Ni, differ from IAB-related irons like Santa Catharina and San Cristobal that contain 25-36 wt.% Ni, as they are highly depleted in moderately volatile siderophiles and enriched in Ir and other refractory elements. Tishomingo and Willow Grove therefore resemble IVB irons but are chemically distinct. The absence of cloudy taenite in these two irons shows that they cooled through 250 degrees C abnormally fast at >0.01 degrees C/yr. Thus this grouplet, like the IVA and IVB irons, suffered an early impact that disrupted their parent body when it was still hot. Our noble gas data show that Tishomingo was excavated from its parent body about 100 to 200 Myr ago and exposed to cosmic rays as a meteoroid with a radius of similar to 50-85 cm.

http://dx.doi.org/10.1016%2Fj.gca.2013.09.023

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